Promotion of iridium-catalyzed methanol carbonylation: Mechanistic studies of the cativa process A Haynes, PM Maitlis, GE Morris, GJ Sunley, H Adams, PW Badger, ... Journal of the American Chemical Society 126 (9), 2847-2861, 2004 | 319 | 2004 |
Methanol carbonylation revisited: thirty years on PM Maitlis, A Haynes, GJ Sunley, MJ Howard Journal of the Chemical Society, Dalton Transactions, 2187-2196, 1996 | 312 | 1996 |
Mechanistic studies on rhodium-catalyzed carbonylation reactions: spectroscopic detection and reactivity of a key intermediate,[MeRh (CO) 2I3]- A Haynes, BE Mann, GE Morris, PM Maitlis Journal of the American Chemical Society 115 (10), 4093-4100, 1993 | 168 | 1993 |
Theoretical and Experimental Evidence for SN2 Transition States in Oxidative Addition of Methyl Iodide to cis-[M(CO)2I2]- (M = Rh, Ir) TR Griffin, DB Cook, A Haynes, JM Pearson, D Monti, GE Morris Journal of the American Chemical Society 118 (12), 3029-3030, 1996 | 161 | 1996 |
Catalytic methanol carbonylation A Haynes Advances in catalysis 53, 1-45, 2010 | 141 | 2010 |
Steric and Electronic Effects on the Reactivity of Rh and Ir Complexes Containing P− S, P− P, and P− O Ligands. Implications for the Effects of Chelate Ligands in Catalysis L Gonsalvi, H Adams, GJ Sunley, E Ditzel, A Haynes Journal of the American Chemical Society 124 (45), 13597-13612, 2002 | 123 | 2002 |
Oxidative addition of alkyl halides to rhodium (I) and iridium (I) dicarbonyl diiodides: key reactions in the catalytic carbonylation of alcohols PR Ellis, JM Pearson, A Haynes, H Adams, NA Bailey, PM Maitlis Organometallics 13 (8), 3215-3226, 1994 | 113 | 1994 |
Theoretical, Thermodynamic, Spectroscopic, and Structural Studies of the Consequences of One-Electron Oxidation on the Fe− X Bonds in 17-and 18-Electron Cp* Fe (dppe) X … M Tilset, I Fjeldahl, JR Hamon, P Hamon, L Toupet, JY Saillard, K Costuas, ... Journal of the American Chemical Society 123 (41), 9984-10000, 2001 | 105 | 2001 |
Direct observation of MeRh (CO) 2I3-, the key intermediate in rhodium-catalyzed methanol carbonylation A Haynes, BE Mann, DJ Gulliver, GE Morris, PM Maitlis Journal of the American Chemical Society 113 (22), 8567-8569, 1991 | 101 | 1991 |
Quantifying steric effects of α-diimine ligands. Oxidative addition of MeI to rhodium (I) and migratory insertion in rhodium (III) complexes L Gonsalvi, JA Gaunt, H Adams, A Castro, GJ Sunley, A Haynes Organometallics 22 (5), 1047-1054, 2003 | 100 | 2003 |
A dramatic steric effect on the rate of migratory CO insertion on rhodium L Gonsalvi, H Adams, GJ Sunley, E Ditzel, A Haynes Journal of the American Chemical Society 121 (48), 11233-11234, 1999 | 92 | 1999 |
Acetic acid synthesis by catalytic carbonylation of methanol A Haynes Catalytic Carbonylation Reactions, 179-205, 2006 | 91 | 2006 |
Oxidative addition of MeI to a rhodium (I) N-heterocyclic carbene complex. A kinetic study HC Martin, NH James, J Aitken, JA Gaunt, H Adams, A Haynes Organometallics 22 (22), 4451-4458, 2003 | 70 | 2003 |
Ligand stereoelectronic effects in complexes of phospholanes, phosphinanes, and phosphepanes and their implications for hydroformylation catalysis RA Baber, MF Haddow, AJ Middleton, AG Orpen, PG Pringle, A Haynes, ... Organometallics 26 (3), 713-725, 2007 | 66 | 2007 |
Iodide effects in transition metal catalyzed reactions PM Maitlis, A Haynes, BR James, M Catellani, GP Chiusoli Dalton Transactions, 3409-3419, 2004 | 63 | 2004 |
Encapsulation of Crabtree's Catalyst in Sulfonated MIL‐101 (Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment A Grigoropoulos, AI McKay, AP Katsoulidis, RP Davies, A Haynes, ... Angewandte Chemie International Edition 57 (17), 4532-4537, 2018 | 62 | 2018 |
A mechanism for the photochemical conversion of FpSi2Me5 to FpSiMe3 (Fp=(. eta. 5-C5H5) Fe (CO) 2). Infrared evidence for an intermediate iron-silylene complex A Haynes, MW George, MT Haward, M Poliakoff, JJ Turner, NM Boag, ... Journal of the American Chemical Society 113 (6), 2011-2020, 1991 | 60 | 1991 |
Encapsulation of an organometallic cationic catalyst by direct exchange into an anionic MOF A Grigoropoulos, GFS Whitehead, N Perret, AP Katsoulidis, FM Chadwick, ... Chemical Science 7 (3), 2037-2050, 2016 | 59 | 2016 |
Bis (imino) carbazolide complexes of rhodium: Highly nucleophilic ligands exerting a dramatic accelerating effect on MeI oxidative addition JA Gaunt, VC Gibson, A Haynes, SK Spitzmesser, AJP White, DJ Williams Organometallics 23 (5), 1015-1023, 2004 | 53 | 2004 |
Mechanistic Study of Rhodium/xantphos-Catalyzed Methanol Carbonylation GL Williams, CM Parks, CR Smith, H Adams, A Haynes, AJHM Meijer, ... Organometallics 30 (22), 6166-6179, 2011 | 52 | 2011 |