| Methane as raw material in synthetic chemistry: the final frontier A Caballero, PJ Pérez Chemical Society Reviews 42 (23), 8809-8820, 2013 | 316 | 2013 |
| Silver-Catalyzed C-C Bond Formation Between Methane and Ethyl Diazoacetate in Supercritical CO2 A Caballero, E Despagnet-Ayoub, M Mar Díaz-Requejo, ... Science 332 (6031), 835-838, 2011 | 257 | 2011 |
| Highly Regioselective Functionalization of Aliphatic Carbon− Hydrogen Bonds with a Perbromohomoscorpionate Copper (I) Catalyst A Caballero, MM Díaz-Requejo, TR Belderraín, MC Nicasio, S Trofimenko, ... Journal of the American Chemical Society 125 (6), 1446-1447, 2003 | 146 | 2003 |
| Catalytic functionalization of low reactive C (sp 3)–H and C (sp 2)–H bonds of alkanes and arenes by carbene transfer from diazo compounds A Caballero, MM Díaz-Requejo, MR Fructos, A Olmos, J Urbano, ... Dalton Transactions 44 (47), 20295-20307, 2015 | 114 | 2015 |
| Ruthenium-catalyzed hydroboration and dehydrogenative borylation of linear and cyclic alkenes with pinacolborane A Caballero, S Sabo-Etienne Organometallics 26 (5), 1191-1195, 2007 | 113 | 2007 |
| Copper (I)− Homoscorpionate Catalysts for the Preferential, Kinetically Controlled Cis Cyclopropanation of α-Olefins with Ethyl Diazoacetate MM Díaz-Requejo, A Caballero, TR Belderraín, MC Nicasio, S Trofimenko, ... Journal of the American Chemical Society 124 (6), 978-983, 2002 | 111 | 2002 |
| Mechanism of Alkane C− H Bond Activation by Copper and Silver Homoscorpionate Complexes AAC Braga, F Maseras, J Urbano, A Caballero, MM Diaz-Requejo, ... Organometallics 25 (22), 5292-5300, 2006 | 100 | 2006 |
| Functionalization of Carbon− Hydrogen Bonds of Hydrocarbons and Ethers via Carbene Insertion with Copper (I)− Homoscorpionate Catalysts A Caballero, MM Díaz-Requejo, TR Belderraín, MC Nicasio, S Trofimenko, ... Organometallics 22 (20), 4145-4150, 2003 | 84 | 2003 |
| A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag) E Despagnet-Ayoub, K Jacob, L Vendier, M Etienne, E Alvarez, ... Organometallics 27 (18), 4779-4787, 2008 | 71 | 2008 |
| Discovering copper for methane C–H bond functionalization R Gava, A Olmos, B Noverges, T Varea, E Álvarez, TR Belderrain, ... ACS Catalysis 5 (6), 3726-3730, 2015 | 66 | 2015 |
| Metal‐catalyzed olefin cyclopropanation with ethyl diazoacetate: control of the diastereoselectivity A Caballero, A Prieto, MM Díaz‐Requejo, PJ Pérez European Journal of Inorganic Chemistry 2009 (9), 1137-1144, 2009 | 65 | 2009 |
| Enantio‐and Diastereoselective Cyclopropanation of 1‐Alkenylboronates: Synthesis of 1‐Boryl‐2, 3‐Disubstituted Cyclopropanes J Carreras, A Caballero, PJ Pérez Angewandte Chemie International Edition 57 (9), 2334-2338, 2018 | 55 | 2018 |
| Copper− Homoscorpionate Complexes as Active Catalysts for Atom Transfer Radical Addition to Olefins JM Muñoz-Molina, A Caballero, MM Díaz-Requejo, S Trofimenko, ... Inorganic chemistry 46 (19), 7725-7730, 2007 | 49 | 2007 |
| Dimensioning the term carbenoid A Caballero, PJ Pérez Chemistry–A European Journal 23 (58), 14389-14393, 2017 | 47 | 2017 |
| Mechanism of side reactions in alkane C H bond functionalization by diazo compounds catalyzed by Ag and Cu homoscorpionate complexes—a DFT study AAC Braga, A Caballero, J Urbano, MM Diaz‐Requejo, PJ Pérez, ... ChemCatChem 3 (10), 1646-1652, 2011 | 47 | 2011 |
| Very efficient, reusable copper catalyst for carbene transfer reactions under biphasic conditions using ionic liquids P Rodríguez, A Caballero, MM Díaz-Requejo, MC Nicasio, PJ Pérez Organic Letters 8 (4), 557-560, 2006 | 42 | 2006 |
| Syntheses of a novel fluorinated trisphosphinoborate ligand and its copper and silver complexes. Catalytic activity toward nitrene transfer reactions I Arenas, MÁ Fuentes, E Alvarez, Y Diaz, A Caballero, S Castillon, ... Inorganic Chemistry 53 (8), 3991-3999, 2014 | 39 | 2014 |
| Copper-catalyzed addition of ethyl diazoacetate to furans: An alternative to dirhodium (II) tetraacetate A Caballero, MM Díaz-Requejo, S Trofimenko, TR Belderrain, PJ Pérez The Journal of Organic Chemistry 70 (15), 6101-6104, 2005 | 39 | 2005 |
| Measuring the relative reactivity of the carbon–hydrogen bonds of alkanes as nucleophiles A Olmos, R Gava, B Noverges, D Bellezza, K Jacob, M Besora, ... Angewandte Chemie International Edition 57 (42), 13848-13852, 2018 | 37 | 2018 |
| Functionalization of Non‐activated C H Bonds of Alkanes: An Effective and Recyclable Catalytic System Based on Fluorinated Silver Catalysts and Solvents MÁ Fuentes, BK Muñoz, K Jacob, L Vendier, A Caballero, M Etienne, ... Chemistry–A European Journal 19 (4), 1327-1334, 2013 | 36 | 2013 |
