The mechanisms of the Stille reaction P Espinet, AM Echavarren Angewandte Chemie International Edition 43 (36), 4704-4734, 2004 | 1266 | 2004 |
Transition metal liquid crystals: advanced materials within the reach of the coordination chemist P Espinet, MA Esteruelas, LA Oro, JL Serrano, E Sola Coordination chemistry reviews 117, 215-274, 1992 | 581 | 1992 |
The Stille reaction, 38 years later C Cordovilla, C Bartolomé, JM Martinez-Ilarduya, P Espinet Acs Catalysis 5 (5), 3040-3053, 2015 | 466 | 2015 |
Phosphine-pyridyl and related ligands in synthesis and catalysis P Espinet, K Soulantica Coordination Chemistry Reviews 193, 499-556, 1999 | 372 | 1999 |
Mechanism of the Stille Reaction. 1. The Transmetalation Step. Coupling of R1I and R2SnBu3 Catalyzed by trans-[PdR1IL2] (R1 = C6Cl2F3; R2 = Vinyl, 4 … AL Casado, P Espinet Journal of the American Chemical Society 120 (35), 8978-8985, 1998 | 359 | 1998 |
On the Configuration Resulting from Oxidative Addition of RX to Pd(PPh3)4 and the Mechanism of the cis-to-trans Isomerization of [PdRX(PPh3)2] Complexes … AL Casado, P Espinet Organometallics 17 (5), 954-959, 1998 | 334 | 1998 |
Unlikeliness of Pd-free gold (I)-catalyzed Sonogashira coupling reactions T Lauterbach, M Livendahl, A Rosellón, P Espinet, AM Echavarren Organic Letters 12 (13), 3006-3009, 2010 | 306 | 2010 |
Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for C C Coupling and Other Reactions MH Pérez‐Temprano, JA Casares, P Espinet Chemistry–A European Journal 18 (7), 1864-1884, 2012 | 238 | 2012 |
Mechanism of the stille reaction. 2. Couplings of aryl triflates with vinyltributyltin. Observation of intermediates. A more comprehensive scheme AL Casado, P Espinet, AM Gallego Journal of the American Chemical Society 122 (48), 11771-11782, 2000 | 236 | 2000 |
C− C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment M Perez-Rodriguez, AAC Braga, M Garcia-Melchor, MH Perez-Temprano, ... Journal of the American Chemical Society 131 (10), 3650-3657, 2009 | 223 | 2009 |
Efficient Synthesis of Chiral 1, 1′‐Binaphthalenes by the Asymmetric Suzuki–Miyaura Reaction: Dramatic Synthetic Improvement by Simple Purification of Naphthylboronic Acids M Genov, A Almorín, P Espinet Chemistry–A European Journal 12 (36), 9346-9352, 2006 | 181 | 2006 |
Die Mechanismen der Stille‐Reaktion P Espinet, AM Echavarren Angewandte Chemie 116 (36), 4808-4839, 2004 | 180 | 2004 |
A warning on the use of radical traps as a test for radical mechanisms: they react with palladium hydrido complexes AC Albéniz, P Espinet, R López-Fernández, A Sen Journal of the American Chemical Society 124 (38), 11278-11279, 2002 | 151 | 2002 |
Insights into the Mechanism of the Negishi Reaction: ZnRX versus ZnR2 Reagents JA Casares, P Espinet, B Fuentes, G Salas Journal of the American Chemical Society 129 (12), 3508-3509, 2007 | 136 | 2007 |
Quantitative evaluation of the factors contributing to the “copper effect” in the Stille reaction AL Casado, P Espinet Organometallics 22 (6), 1305-1309, 2003 | 134 | 2003 |
Nitrogen acyclic gold (I) carbenes: Excellent and easily accessible catalysts in reactions of 1, 6-enynes C Bartolome, Z Ramiro, D Garcia-Cuadrado, P Perez-Galan, M Raducan, ... Organometallics 29 (4), 951-956, 2010 | 130 | 2010 |
A Novel Approach to Ferroelectric Liquid Crystals: the First Organotransition Metal Compound Displaying This Behavior P Espinet, J Etxebarría, M Marcos, J Pérez, A Remón, JL Serrano Angewandte Chemie International Edition in English 28 (8), 1065-1066, 1989 | 129 | 1989 |
A critical analysis of the cyclic and open alternatives of the transmetalation step in the Stille cross-coupling reaction A Nova, G Ujaque, F Maseras, A Lledós, P Espinet Journal of the American Chemical Society 128 (45), 14571-14578, 2006 | 119 | 2006 |
Mesogenic behavior of silver thiolates with layered structure in the solid state: covalent soaps MJ Baena, P Espinet, MC Lequerica, AM Levelut Journal of the American Chemical Society 114 (11), 4182-4185, 1992 | 115 | 1992 |
Bonding modes in palladium (II) enolates: consequences for dynamic behavior and reactivity AC Albéniz, NM Catalina, P Espinet, R Redón Organometallics 18 (26), 5571-5576, 1999 | 110 | 1999 |