Pablo Espinet
Pablo Espinet
Chair Professor
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The mechanisms of the Stille reaction
P Espinet, AM Echavarren
Angewandte Chemie International Edition 43 (36), 4704-4734, 2004
Transition metal liquid crystals: advanced materials within the reach of the coordination chemist
P Espinet, MA Esteruelas, LA Oro, JL Serrano, E Sola
Coordination chemistry reviews 117, 215-274, 1992
Phosphine-pyridyl and related ligands in synthesis and catalysis
P Espinet, K Soulantica
Coordination Chemistry Reviews 193, 499-556, 1999
Mechanism of the Stille Reaction. 1. The Transmetalation Step. Coupling of R1I and R2SnBu3 Catalyzed by trans-[PdR1IL2] (R1 = C6Cl2F3; R2 = Vinyl, 4 …
AL Casado, P Espinet
Journal of the American Chemical Society 120 (35), 8978-8985, 1998
Recent progress on the stereoselective synthesis of acyclic quaternary α-amino acids
C Cativiela, MD Díaz-de-Villegas
Tetrahedron: Asymmetry 18 (5), 569-623, 2007
On the Configuration Resulting from Oxidative Addition of RX to Pd(PPh3)4 and the Mechanism of the cis-to-trans Isomerization of [PdRX(PPh3)2] Complexes …
AL Casado, P Espinet
Organometallics 17 (5), 954-959, 1998
Unlikeliness of Pd-free gold (I)-catalyzed Sonogashira coupling reactions
T Lauterbach, M Livendahl, A Rosellón, P Espinet, AM Echavarren
Organic Letters 12 (13), 3006-3009, 2010
The Stille reaction, 38 years later
C Cordovilla, C Bartolomé, JM Martínez-Ilarduya, P Espinet
Acs Catalysis 5 (5), 3040-3053, 2015
Mechanism of the stille reaction. 2. Couplings of aryl triflates with vinyltributyltin. Observation of intermediates. A more comprehensive scheme
AL Casado, P Espinet, AM Gallego
Journal of the American Chemical Society 122 (48), 11771-11782, 2000
C− C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment
M Perez-Rodriguez, AAC Braga, M Garcia-Melchor, MH Perez-Temprano, ...
Journal of the American Chemical Society 131 (10), 3650-3657, 2009
Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for C? C Coupling and Other Reactions
MH Pérez‐Temprano, JA Casares, P Espinet
Chemistry–A European Journal 18 (7), 1864-1884, 2012
Die Mechanismen der Stille‐Reaktion
P Espinet, AM Echavarren
Angewandte Chemie 116 (36), 4808-4839, 2004
Efficient Synthesis of Chiral 1, 1′‐Binaphthalenes by the Asymmetric Suzuki–Miyaura Reaction: Dramatic Synthetic Improvement by Simple Purification of Naphthylboronic Acids
M Genov, A Almorín, P Espinet
Chemistry–A European Journal 12 (36), 9346-9352, 2006
A Novel Approach to Ferroelectric Liquid Crystals: the First Organotransition Metal Compound Displaying This Behavior
P Espinet, J Etxebarría, M Marcos, J Pérez, A Remón, JL Serrano
Angewandte Chemie International Edition in English 28 (8), 1065-1066, 1989
A warning on the use of radical traps as a test for radical mechanisms: they react with palladium hydrido complexes
AC Albéniz, P Espinet, R López-Fernández, A Sen
Journal of the American Chemical Society 124 (38), 11278-11279, 2002
Insights into the Mechanism of the Negishi Reaction:  ZnRX versus ZnR2 Reagents
JA Casares, P Espinet, B Fuentes, G Salas
Journal of the American Chemical Society 129 (12), 3508-3509, 2007
Quantitative evaluation of the factors contributing to the “copper effect” in the stille reaction
AL Casado, P Espinet
Organometallics 22 (6), 1305-1309, 2003
Nitrogen acyclic gold (I) carbenes: Excellent and easily accessible catalysts in reactions of 1, 6-enynes
C Bartolomé, Z Ramiro, D García-Cuadrado, P Pérez-Galán, M Raducan, ...
Organometallics 29 (4), 951-956, 2010
Mesogenic behavior of silver thiolates with layered structure in the solid state: covalent soaps
MJ Baena, P Espinet, MC Lequerica, AM Levelut
Journal of the American Chemical Society 114 (11), 4182-4185, 1992
A critical analysis of the cyclic and open alternatives of the transmetalation step in the Stille cross-coupling reaction
A Nova, G Ujaque, F Maseras, A Lledós, P Espinet
Journal of the American Chemical Society 128 (45), 14571-14578, 2006
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