Introducing deep eutectic solvents to polar organometallic chemistry: chemoselective addition of organolithium and grignard reagents to ketones in air C Vidal, J García‐Álvarez, A Hernán‐Gómez, AR Kennedy, E Hevia Angewandte Chemie 126 (23), 6079-6083, 2014 | 186 | 2014 |
Deep eutectic mixtures: Promising sustainable solvents for metal‐catalysed and metal‐mediated organic reactions J García‐Álvarez European Journal of Inorganic Chemistry 2015 (31), 5147-5157, 2015 | 144 | 2015 |
A highly efficient copper (I) catalyst for the 1, 3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes in water: regioselective synthesis of 1, 4-disubstituted and … J Garcia-Alvarez, J Diez, J Gimeno Green chemistry 12 (12), 2127-2130, 2010 | 138 | 2010 |
Exploiting deep eutectic solvents and organolithium reagent partnerships: chemoselective ultrafast addition to imines and quinolines under aerobic ambient temperature conditions C Vidal, J García‐Álvarez, A Hernán‐Gómez, AR Kennedy, E Hevia Angewandte Chemie International Edition 55 (52), 16145-16148, 2016 | 133 | 2016 |
The future of polar organometallic chemistry written in bio‐based solvents and water J García‐Álvarez, E Hevia, V Capriati Chemistry–A European Journal 24 (56), 14854-14863, 2018 | 109 | 2018 |
Programming cascade reactions interfacing biocatalysis with transition-metal catalysis in Deep Eutectic Solvents as biorenewable reaction media L Cicco, N Ríos-Lombardía, MJ Rodríguez-Álvarez, F Morís, FM Perna, ... Green chemistry 20 (15), 3468-3475, 2018 | 101 | 2018 |
Alkali-metal-mediated zincation (AMMZn) meets N-heterocyclic carbene (NHC) chemistry: Zn–H exchange reactions and structural authentication of a dinuclear Au (I) complex with a … DR Armstrong, SE Baillie, VL Blair, NG Chabloz, J Diez, J Garcia-Alvarez, ... Chemical Science 4 (11), 4259-4266, 2013 | 86 | 2013 |
Deep eutectic solvents: biorenewable reaction media for Au (I)-catalysed cycloisomerisations and one-pot tandem cycloisomerisation/Diels–Alder reactions C Vidal, L Merz, J García-Álvarez Green chemistry 17 (7), 3870-3878, 2015 | 83 | 2015 |
Glycerol: a biorenewable solvent for base-free Cu (I)-catalyzed 1, 3-dipolar cycloaddition of azides with terminal and 1-iodoalkynes. Highly efficient transformations and … C Vidal, J García-Álvarez Green chemistry 16 (7), 3515-3521, 2014 | 83 | 2014 |
Alkali-metal-mediated manganation: a method for directly attaching manganese (II) centers to aromatic frameworks RE Mulvey, J Garcia-Alvarez, AR Kennedy, J Klett Angewandte Chemie 46 (7), 1105-1108, 2007 | 71 | 2007 |
Recent progress of Cu-catalyzed azide-alkyne cycloaddition reactions (CuAAC) in sustainable solvents: Glycerol, deep eutectic solvents, and aqueous media N Nebra, J García-Álvarez Molecules 25 (9), 2015, 2020 | 67 | 2020 |
Iminophosphorane–phosphines: Versatile ligands for homogeneous catalysis J Garcia-Alvarez, SE Garcia-Garrido, V Cadierno Journal of Organometallic Chemistry 751, 792-808, 2014 | 67 | 2014 |
Introducing deep eutectic solvents as biorenewable media for Au (I)-catalysed cycloisomerisation of γ-alkynoic acids: An unprecedented catalytic system MJ Rodríguez-Álvarez, C Vidal, J Díez, J García-Álvarez Chemical communications 50 (85), 12927-12929, 2014 | 67 | 2014 |
Reactivity of polar organometallic compounds in unconventional reaction media: challenges and opportunities J García‐Álvarez, E Hevia, V Capriati European Journal of Organic Chemistry 2015 (31), 6779-6799, 2015 | 65 | 2015 |
One-pot sustainable synthesis of tertiary alcohols by combining ruthenium-catalysed isomerisation of allylic alcohols and chemoselective addition of polar organometallic … L Cicco, MJ Rodríguez-Álvarez, FM Perna, J García-Álvarez, V Capriati Green chemistry 19 (13), 3069-3077, 2017 | 62 | 2017 |
From a sequential to a concurrent reaction in aqueous medium: ruthenium‐catalyzed allylic alcohol isomerization and asymmetric bioreduction N Ríos‐Lombardía, C Vidal, E Liardo, F Morís, J García‐Álvarez, ... Angewandte Chemie 128 (30), 8833-8837, 2016 | 62 | 2016 |
Synthetic and structural insights into the zincation of toluene: direct synergic ring metallation versus indirect nonsynergic lateral metallation DR Armstrong, J García‐Álvarez, DV Graham, GW Honeyman, E Hevia, ... Chemistry–A European Journal 15 (15), 3800-3807, 2009 | 62 | 2009 |
Deep eutectic solvents (DES) as green reaction media for the redox isomerization of allylic alcohols into carbonyl compounds catalyzed by the ruthenium complex [Ru (η3: η3 … C Vidal, FJ Suárez, J García-Álvarez Catalysis Communications 44, 76-79, 2014 | 59 | 2014 |
Redox Isomerization of Allylic Alcohols into Carbonyl Compounds Catalyzed by the Ruthenium(IV) Complex [Ru(η3:η3-C10H16)Cl(κ2O,O-CH3CO2)] in … J Garcia-Alvarez, J Gimeno, FJ Suarez Organometallics 30 (10), 2893-2896, 2011 | 58 | 2011 |
Chemoenzymatic one-pot synthesis in an aqueous medium: combination of metal-catalysed allylic alcohol isomerisation–asymmetric bioamination N Ríos-Lombardía, C Vidal, M Cocina, F Morís, J García-Álvarez, ... Chemical communications 51 (54), 10937-10940, 2015 | 55 | 2015 |