Ligand-controlled regioselectivity in the hydrothiolation of alkynes by rhodium N-heterocyclic carbene catalysts A Di Giuseppe, R Castarlenas, JJ Pérez-Torrente, M Crucianelli, V Polo, ... Journal of the American Chemical Society 134 (19), 8171-8183, 2012 | 176 | 2012 |
The Emergence of Transition‐Metal‐Mediated Hydrothiolation of Unsaturated Carbon–Carbon Bonds: A Mechanistic Outlook R Castarlenas, A Di Giuseppe, JJ Pérez‐Torrente, LA Oro Angewandte Chemie International Edition 52 (1), 211-222, 2013 | 164 | 2013 |
N-Heterocyclic Carbene− Osmium Complexes for Olefin Metathesis Reactions R Castarlenas, MA Esteruelas, E Oñate Organometallics 24 (18), 4343-4346, 2005 | 164 | 2005 |
Allenylidene-to-indenylidene rearrangement in arene− ruthenium complexes: A key step to highly active catalysts for olefin metathesis reactions R Castarlenas, C Vovard, C Fischmeister, PH Dixneuf Journal of the American Chemical Society 128 (12), 4079-4089, 2006 | 132 | 2006 |
Preparation, X-ray structure, and reactivity of an osmium-hydroxo complex stabilized by an N-heterocyclic carbene ligand: A base-free catalytic precursor for hydrogen transfer … R Castarlenas, MA Esteruelas, E Onate Organometallics 27 (13), 3240-3247, 2008 | 102 | 2008 |
Reactions of a Hexahydride− Osmium Complex with Aromatic Ketones: C− H Activation versus C− F Activation P Barrio, R Castarlenas, MA Esteruelas, A Lledós, F Maseras, E Oñate, ... Organometallics 20 (3), 442-452, 2001 | 102 | 2001 |
Highly active catalysts in alkene metathesis: first observed transformation of allenylidene into indenylidene via alkenylcarbyne—ruthenium species R Castarlenas, PH Dixneuf Angewandte Chemie International Edition 42 (37), 4524-4527, 2003 | 94 | 2003 |
Mild and selective H/D exchange at the β position of aromatic α-olefins by N-heterocyclic carbene-hydride-rhodium catalysts A Giuseppe, R Castarlenas, JJ Pérez-Torrente, FJ Lahoz, V Polo, LA Oro Wiley-VCH, 2011 | 90 | 2011 |
Assembly of an allenylidene ligand, a terminal alkyne, and an acetonitrile molecule: Formation of osmacyclopentapyrrole derivatives T Bolaño, R Castarlenas, MA Esteruelas, E Oñate Journal of the American Chemical Society 128 (12), 3965-3973, 2006 | 89 | 2006 |
Hydride-alkenylcarbyne to alkenylcarbene transformation in bisphosphine-osmium complexes T Bolaño, R Castarlenas, MA Esteruelas, FJ Modrego, E Oñate Journal of the American Chemical Society 127 (31), 11184-11195, 2005 | 79 | 2005 |
Triple C− H Activation of a Cycloalkyl Ketone Using an Osmium− Hexahydride Complex P Barrio, R Castarlenas, MA Esteruelas, E Oñate Organometallics 20 (12), 2635-2638, 2001 | 77 | 2001 |
Allenylidene–ruthenium complexes as versatile precatalysts for alkene metathesis reactions R Castarlenas, C Fischmeister, C Bruneau, PH Dixneuf Journal of Molecular Catalysis A: Chemical 213 (1), 31-37, 2004 | 76 | 2004 |
Allenylidene-ruthenium-arene precatalyst for ring opening metathesis polymerisation (ROMP) R Castarlenas, D Sémeril, AF Noels, A Demonceau, PH Dixneuf Journal of organometallic chemistry 663 (1-2), 235-238, 2002 | 76 | 2002 |
Δ2- and Δ3-Azaosmetine Complexes as Intermediates in the Stoichiometric Imination of Phenylacetylene with Oximes R Castarlenas, MA Esteruelas, E Oñate Organometallics 20 (11), 2294-2302, 2001 | 71 | 2001 |
Preparation and Structure of Alkylidene− Osmium and Hydride− Alkylidyne− Osmium Complexes Containing an N-Heterocyclic Carbene Ligand R Castarlenas, MA Esteruelas, E Oñate Organometallics 26 (8), 2129-2132, 2007 | 63 | 2007 |
Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C–H Activation R Azpíroz, L Rubio-Pérez, A Di Giuseppe, V Passarelli, FJ Lahoz, ... ACS Catalysis 4 (12), 4244-4253, 2014 | 61 | 2014 |
Reactivity of the Imine−Vinylidene Complexes OsCl2(CCHPh)(NHCR2)(PiPr3)2 [CR2 = CMe2, C(CH2)4CH2] R Castarlenas, MA Esteruelas, E Gutiérrez-Puebla, E Oñate Organometallics 20 (8), 1545-1554, 2001 | 57 | 2001 |
Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand A Di Giuseppe, R De Luca, R Castarlenas, JJ Pérez-Torrente, ... Chemical communications 52 (32), 5554-5557, 2016 | 55 | 2016 |
Hydroxo–rhodium–N-heterocyclic carbene complexes as efficient catalyst precursors for alkyne hydrothiolation L Palacios, MJ Artigas, V Polo, FJ Lahoz, R Castarlenas, ... Acs Catalysis 3 (12), 2910-2919, 2013 | 55 | 2013 |
Hydride-carbyne to carbene transformation in an osmium-acetate-bis (triisopropylphosphine) system: Influence of the coordination mode of the carboxylate and the reaction solvent T Bolaño, R Castarlenas, MA Esteruelas, E Oñate Organometallics 26 (8), 2037-2041, 2007 | 55 | 2007 |