Bimetallic Catalysis using Transition and Group 11 Metals: An Emerging Tool for C C Coupling and Other Reactions MH Pérez‐Temprano, JA Casares, P Espinet Chemistry–A European Journal 18 (7), 1864-1884, 2012 | 239 | 2012 |
C− C reductive elimination in palladium complexes, and the role of coupling additives. A DFT study supported by experiment M Perez-Rodriguez, AAC Braga, M Garcia-Melchor, MH Perez-Temprano, ... Journal of the American Chemical Society 131 (10), 3650-3657, 2009 | 223 | 2009 |
C(sp3)–O Bond-Forming Reductive Elimination from PdIV with Diverse Oxygen Nucleophiles NM Camasso, MH Perez-Temprano, MS Sanford Journal of the American Chemical Society 136 (36), 12771-12775, 2014 | 106 | 2014 |
Competition between sp3-C–N vs sp3-C–F Reductive Elimination from PdIV Complexes MH Perez-Temprano, JM Racowski, JW Kampf, MS Sanford Journal of the American Chemical Society 136 (11), 4097-4100, 2014 | 106 | 2014 |
Emerging unconventional organic solvents for C–H bond and related functionalization reactions C Yu, J Sanjosé-Orduna, FW Patureau, MH Pérez-Temprano Chemical Society Reviews 49 (6), 1643-1652, 2020 | 96 | 2020 |
Experimental and Computational Assessment of Reactivity and Mechanism in C(sp3)–N Bond-Forming Reductive Elimination from Palladium(IV) IM Pendleton, MH Perez-Temprano, MS Sanford, PM Zimmerman Journal of the American Chemical Society 138 (18), 6049-6060, 2016 | 91 | 2016 |
Stille coupling involving bulky groups feasible with gold cocatalyst. J delPozo, D Carrasco, MH Pérez‐Temprano, M García‐Melchor, ... Angewandte Chemie 125 (8), 2013 | 71 | 2013 |
Strong metallophilic interactions in the palladium arylation by gold aryls. MH Pérez-Temprano, JA Casares, ÁR de Lera, R Álvarez, P Espinet Angewandte Chemie (International ed. in English) 51 (20), 4917-4920, 2012 | 59 | 2012 |
Capturing Elusive Cobaltacycle Intermediates: A Real‐Time Snapshot of the Cp*CoIII‐Catalyzed Oxidative Alkyne Annulation J Sanjosé‐Orduna, D Gallego, A Garcia‐Roca, E Martin, ... Angewandte Chemie International Edition 56 (40), 12137-12141, 2017 | 57 | 2017 |
Beyond the traditional roles of Ag in catalysis: the transmetalating ability of organosilver (I) species in Pd-catalysed reactions ÁL Mudarra, SM de Salinas, MH Pérez-Temprano Organic & Biomolecular Chemistry 17 (7), 1655-1667, 2019 | 54 | 2019 |
HFIP‐Assisted C−H Functionalization by Cp*CoIII: Access to Key Reactive Cobaltacycles and Implication in Catalysis J Sanjosé‐Orduna, JM Sarria Toro, MH Pérez‐Temprano Angewandte Chemie International Edition 57 (35), 11369-11373, 2018 | 51 | 2018 |
Observation of a hidden intermediate in the Stille reaction. Study of the reversal of the transmetalation step MH Pérez-Temprano, A Nova, JA Casares, P Espinet Journal of the American Chemical Society 130 (32), 10518-10520, 2008 | 45 | 2008 |
Stille coupling of alkynyl stannane and aryl iodide, a many-pathways reaction: the importance of isomerization MH Perez-Temprano, AM Gallego, JA Casares, P Espinet Organometallics 30 (3), 611-617, 2011 | 40 | 2011 |
Weakly Coordinated Cobaltacycles: Trapping Catalytically Competent Intermediates in Cp*CoIII Catalysis S Martínez de Salinas, J Sanjosé‐Orduna, C Odena, S Barranco, ... Angewandte Chemie International Edition 59 (15), 6239-6243, 2020 | 37 | 2020 |
Unravelling Molecular Aspects of the Migratory Insertion Step in Cp*CoIII Metallacyclic Systems J Sanjosé-Orduna, J Benet-Buchholz, MH Pérez-Temprano Inorganic Chemistry 58 (16), 10569-10577, 2019 | 29 | 2019 |
New Vistas in Transmetalation with Discrete “AgCF3” Species: Implications in Pd‐Mediated Trifluoromethylation Reactions S Martínez de Salinas, ÁL Mudarra, J Benet‐Buchholz, T Parella, ... Chemistry–A European Journal 24 (46), 11895-11898, 2018 | 27 | 2018 |
Exploring the role of coinage metalates in trifluoromethylation: a combined experimental and theoretical study S Martínez de Salinas, ÁL Mudarra, C Odena, M Martínez Belmonte, ... Chemistry–A European Journal 25 (40), 9390-9394, 2019 | 23 | 2019 |
Nucleophilic Trifluoromethylation Reactions Involving Copper (I) Species: From Organometallic Insights to Scope ÁL Mudarra, SM de Salinas, MH Pérez-Temprano Synthesis 51 (14), 2809-2820, 2019 | 22 | 2019 |
Transition metal-catalysed directed C–H functionalization with nucleophiles S Barranco, J Zhang, S López-Resano, A Casnati, MH Pérez-Temprano Nature Synthesis 1 (11), 841-853, 2022 | 19 | 2022 |
Redefining the Mechanistic Scenario of Carbon–Sulfur Nucleophilic Coupling via High‐Valent Cp* Co (IV) Species S López-Resano, SM de Salinas, FA Garcés-Pineda, A Moneo-Corcuera, ... Angewandte Chemie International Edition 60 (20), 11217-11221, 2021 | 19 | 2021 |